Neet Chemistry Neet Chemistry 1 / 119 1 gram of sodium hydroxide was treated with 25 mL of 0.75 M HCl solution, the mass of sodium hydroxide left unreacted is equal to : Zero mg 200 mg 750 mg 250 mg 2 / 119 The highest number of helium atoms is in : 4g of helium 2.271098 L of helium at STP 4 mol of helium 4u of helium 3 / 119 A compound X contains 32% of A, 20% of B and remaining percentage of C. Then, the empirical formula of X is: (Given atomic masses of A = 64 B = 40 C = 32u ) $$AB_2C_2$$ $$AB_2C_2$$ $$ABC_4$$ $$A_2BC_2$$ $$ABC_3$$ 4 / 119 The right option for the mass of CO2 produced by heating 20 g of 20% pure limestone is : (Atomic mass of Ca = 40 ) $$\lbrack CaCO_3\;\xrightarrow{1200K}CaO\;+\;CO_2\;\rbrack$$ 1.76 g 2.64 g 1.32 g 1.12 g 5 / 119 What mass of 95% pure CaCO3 will be required to neutralise 50 mL of 0.5 M HCl solution according to the following reaction? $$CaCO_3(s)\;+\;2HCl(aq)\;\rightarrow\;CaCl_2(aq)\;+\;CO_2(g)\;+\;H_2O(l)$$ [Calculate upto second place of decimal point] 1.32 g 3.65 g 9.50 g 1.25 g 6 / 119 An organic compound contains 78% (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of C is 12, H is 1] $$CH_4$$ $$CH$$ $$CH_2$$ $$CH_3$$ 7 / 119 Which one of the following has maximum number of atoms ? 1g of Ag(s) [Atomic mass of Ag = 108 ] 1g of Mg(s) [Atomic mass of Mg = 24 ] 1g of O2(g) [Atomic mass of O = 16 ] 1g of Li(s) [Atomic mass of Li = 7 ] 8 / 119 The number of moles of hydrogen molecules required to produce 20 moles of ammonia through Haber's process is : 40 10 20 30 9 / 119 The density of 2M aqueous solution of NaOH is $$1.28g\;/\;cm^3$$. The molality of the solution is : Given that molecular mass of $$NaOH\;=\;40\;g\;mol^{-1}$$ 1.20 m 1.56 m 1.67 m 1.32 m 10 / 119 In which case is number of molecules of water maximum? 18 mL of water 0.18 g of water 0.00224 L of water vapours at 1 atm and 273 K $$10^{-3}$$mol of water 11 / 119 Calculate the energy in joule corresponding to light of wavelength 45 nm: (a) (b) (c) (d) 12 / 119 A particular station of All India Radio, New Delhi, broadcasts on a frequency of 1,368 kHz (kilohertz). The wavelength of the electromagnetic radiation emitted by the transmitter is: 21.92 cm 219.3 m 219.2 m 2192 m 13 / 119 Select the correct statements from the following: (A) Atoms of all elements are composed of two fundamental particles. (B) The mass of the electron is . (C) All the isotopes of a given elements show same chemical properties. (D) Protons and electrons are collectively known as nucleons. (E) Dalton's atomic theory, regarded the atom as an ultimate particle of matter. Choose the correct answer from the options given below: (C), (D) and (E) only (A) and (E) only (B), (C) and (E) only (A), (B) and (C) only 14 / 119 According to law of photochemical equivalence the energy absorbed (in ergs/mol) is given as (a) (b) (c) (d) 15 / 119 In the photo-electron emission, the energy of the emitted electron is : greater than the incident photon same as that of the incident photon smaller than the incident photon proportional to the intensity of incident photon 16 / 119 If the energy of a photon is given as $$3.03\times10^{-19}J$$ then, the wavelength $$\left(\lambda\right)$$ of the photon is : 6.56 nm 65.6 nm 656 nm 0.656 nm 17 / 119 The value of Planck's constant is $$6.63\times10^{-34}\;Js$$. The velocity of light is $$3.08\times10^8\;ms^{-1}$$ . Which value is closest to the wavelength in nanometres of a quantum of light with frequency of $$8\times10^{15}\;s^{-1}$$ ? (a) (b) (c) (d) 18 / 119 The energy absorbed by each molecule $$(A_2)$$ of a substance is $$4.4\times10^{-19}J$$ and bond energy per molecule is $$4.4\times10^{-19}J$$. The kinetic energy of the molecule per atom will be : (a) (b) (c) (d) 19 / 119 The energies of two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths i.e., will be: (a) (b) (c) (d) 20 / 119 Arrange the following elements in increasing order of first ionization enthalpy : Li, Be, B, C, N Choose the correct answer from the options given below: Li < Be < C < B < N Li < Be < N < B < C Li < Be < B < C < N Li < B < Be < C < N 21 / 119 Arrange the following elements in increasing order of electronegativity: N, O, F, C, Si Choose the correct answer from the options given below: 0 < F < N < C < Si F < O < N < C < Si Si < C < N < 0 < F Si < C < O < N < F 22 / 119 If the atomic number of an element is 33, It will be placed in the periodic table in the : first group third group fifth (or 15th) group seventh group 23 / 119 The electronic configuration of an element is . What is the atomic number of the element, which is just below the above element in the periodic table ? 33 34 36 49 24 / 119 The element, with atomic number 118, will be : alkali noble gas lanthanide transition element 25 / 119 An atom has electronic configuration , you will place it in which group ? Fifth Fifteenth Second Third 26 / 119 The element Z = 114 has been discovered recently it will belong to which of the following family/group and electronic configuration? Carbon family, [Rn] Oxygen family, [Rn] Nitrogen family ,[Rn] Halogen family, [Rn] 27 / 119 Match the following: Oxide Nature (A) CO (i) Basic (B) BaO (ii) Neutral (C) (iii) Acidic (D) (iv) Amphoteric Which of the following is correct option ? A - (ii), B - (i), C - (iv), D - (iii) A - (iii), B - (iv), C - (i), D - (ii) A - (iv), B - (iii), C - (ii), D- (i) A - (i), B - (ii), C - (iii), D- (iv) 28 / 119 Identify the incorrect match: Name IUPAC Official Name (A) Unnilunium (i) Mendelevium (B) Unnitrium (ii) Lawrencium (C) Unnilhexium (iii) Seaborgium (D) Unununnium (iv) Darmstaditium (B), (ii) (C), (iii) (D), (iv) (A), (i) 29 / 119 The IUPAC name of an element with atomic number 119 is: unnilennium unununnium ununoctium ununennium 30 / 119 Which of the following does not apply to metallic bond ? Overlapping valence orbitals Mobile valence electrons Delocalized electrons Highly directed bonds 31 / 119 Among , the covalent bond character follows the order : (a) (b) (c) (d) 32 / 119 Among the following which compound will show the highest lattice energy ? KF NaF CsF RbF 33 / 119 Strongest bond is in between : CsF NaCl Both (a) and (b) None of these 34 / 119 The weakest among the following types of bonds is : ionic covalent metallic H-bond 35 / 119 Which of the following pairs will form the most stable ionic bond ? Na and Cl Mg and F Li and F Na and F 36 / 119 Linus Pauling received the Nobel Prize for his work on: atomic structure photosynthesis chemical bonds thermodynamics 37 / 119 Which of the following compounds has a 3-centre bond? Diborane Carbon dioxide Boron trifluoride Ammonia 38 / 119 Cation and anion combines in a crystal to form following type of compound: ionic metallic covalent dipole-dipole 39 / 119 The correct sequence of increasing covalent character is represented by: (a) (b) (c) (d) 40 / 119 The heat of combustion of carbon tois - 393.5kJ / mol . The heat released upon formation of 35.2 g of from carbon and oxygen gas is: -315 kJ +315 kJ -630 kJ -3.15 kJ 41 / 119 A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy of the gas in joules will be : -500 J -505 J +505 J 1136.25 42 / 119 Under isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is: [Given that 1 L - bar = 100J ] -30J 5kJ 25J 30J 43 / 119 Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure. AB→ Isothermal expansion AC→ Adiabatic expansion Which of the following options is not correct? (a) (b) (c) (d) 44 / 119 An ideal gas expands isothermally from against a constant pressure of . The work done on the gas is: -900 kJ +270 kJ -900 J +900 kJ 45 / 119 The correct option for free expansion of an ideal gas under adiabatic condition is: (a) (b) (c) (d) 46 / 119 Which one among the following is the correct option for right relationship between for one mole of ideal gas ? (a) (b) (c) (d) 47 / 119 Which amongst the following options is the correct relation between change in enthalpy and change in internal energy? (a) (b) (c) (d) 48 / 119 The work done during reversible isothermal expansion of one mole of hydrogen gas at from pressure of 20 atmosphere to 10 atmosphere is: 413.14 calories 100 calories 0 calorie 413.14 calories 49 / 119 Match List I with List II. List I (Process) List II (Conditions) A. Isothermal process I. No heat exchange B. Isochoric process II. Carried out at constant temperature C. Isobaric process III. Carried out at constant volume D. Adiabatic process IV. Carried out at constant pressure Choose the correct answer from the options given below: A-I, B-II, C-III, D-IV A-II, B-III, C-IV, D-I A-IV, B-III, C-II, D-I A-IV, B-II, C-III, D-I 50 / 119 Identify the correct order of solubility in aqueous medium : (a) (b) (c) (d) 51 / 119 The value of $$K_{sp}$$ of $$CaCO_3$$ and $$CaC_2O_4$$ are $$4.7\times10^{-9}$$ respectively at $$25^\textdegree C$$. If the mixture of these two is washed with water, what is the concentration of $$Ca^{2+}$$ ions in water? (a) (b) (c) (d) 52 / 119 Identify the correct order of solubility in aqueous medium: (a) (b) (c) (d) 53 / 119 Using the Gibbs' energy change, , for the following reaction, the in water at is: (a) (b) (c) (d) 54 / 119 Which one of the following pairs of solution is not an acidic buffer? (a) (b) (c) (d) 55 / 119 The are respectively, Which one of the following salts will precipitate last if solution is added to the solution containing equal moles of ? AgCl AgBr (c) Agl 56 / 119 Consider the nitration of benzene using mixed conc. of . If a large amount of is added to the mixture, the rate of nitration will be: faster slower unchanged doubled doubled 57 / 119 Concentration of the $$Ag^+$$ ions in a saturated solution of $$Ag_2C_2O_4$$ is $$2.2\times10^{-4}$$. Solubility product of $$2.2\times10^{-4}\;mol\;L^{-1}$$ is: (a) (b) (c) (d) 58 / 119 The solubility of in water is . The value of its solubility product will be: (a) (b) (c) (d) 59 / 119 pH of a saturated solution of is 9. The solubility product Is : (a) (b) (c) (d) 60 / 119 A compound contains atoms of three elements A, B and C. If the oxidation number of A is +2, B is +5, and that of C is -2, the possible formula of the compound is : (a) (b) (c) (d) 61 / 119 (a) (b) (c) (d) 62 / 119 + 3 ,+6 and + 5 + 5, +3 and + 6 - 3, + 6 and + 6 +5, +6 and + 6 63 / 119 +4 -6 +12 +6 64 / 119 What is the change in oxidation number of carbon in the following reaction? 0 to +4 0 to +4 -4 to +4 0 to-4 +4 and +4 65 / 119 The loss of electron is termed as: oxidation reduction combustion neutralization 66 / 119 Which of the following involves a redox reaction? (a) Production of ozone from oxygen in the atmosphere by lightning Production of nitrogen oxides from nitrogen and oxygen in the atmosphere by lightning Evaporation of water 67 / 119 Zn gives H2 gas with and HCl but not with because : (a) (b) In electrochemical series, Zn is above hydrogen (d) 68 / 119 Which of the following reactions is the metal displacement reaction? (Choose the right option.) (a) (b) (c) (d) 69 / 119 Which reaction is NOT a redox reaction? (a) (b) (c) (d) 70 / 119 In borax bead test which compound is formed? Ortho-borate Meta-borate Double oxide Tetra-borate 71 / 119 Choose the right answer (a) (b) (c) (d) 72 / 119 Choose the right answer (a) (b) (c) (d) 73 / 119 Choose the right answer (a) (b) (c) (d) 74 / 119 Which of the following structure is similar to graphite? B (b) (c) BN 75 / 119 The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence: Ga < In < Al < TI Al < Ga <ln<Tl Tl < In < Ga < Al InTlGa < Al 76 / 119 Which one of the following elements is unable to form $$MF_6^{3-}$$ Ga Al In B 77 / 119 Aluminium chloride in acidified aqueous solution forms a complex 'A', in which hybridisation state of Al is 'B'. What are 'A' and 'B', respectively? (a) (b) (c) (d) 78 / 119 Which of the following statement is not correct about diborane? The four terminal B-H bonds are two centre two electron bonds. The four terminal hydrogen atoms and the two boron atoms lie in one plane. (c) There are two 3-centre-2-electron bonds. 79 / 119 Taking stability as the factor, which one of the following represents correct relationship? (a) (b) (c) (d) 80 / 119 The correct IUPAC name of the compound: 4-Ethyl-3-propyl hex-1-ene 3-Ethyl-4-ethenyl heptane 3-Ethyl-4-propyl hex-1-ene 3-(1-ethylpropyl) hex-1-ene 81 / 119 Which nomenclature is not according to IUPAC system ? (a) (b) (c) (d) 82 / 119 The structure of isobutyl group in an organic compound is : (a) (b) (c) (d) 83 / 119 Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is: (a) (b) (c) (b) 84 / 119 The IUPAC name of the compound is : 5-formylhex-2-en-3-one 5-methyl-4-oxohex-2-en-5-al 3-keto-2-methylhex-5-enal 3-keto-2-methylhex-4-enal 85 / 119 The correct structure of 2, 6-Dimethyl-dec-4-ene is : (a) (b) (c) (d) 86 / 119 The correct IUPAC name of the following compound is: 6 -bromo -2-chloro -1-methylhexan -1-ol 1-bromo-4-methyl-5-chlorohexan-3-ol 6 -bromo -4-methyl -2- chlorohexan -4 -ol 1 -bromo -5-chloro -4-methylhexan -3 -ol 87 / 119 In Lassaigne's extract of an organic compound, both nitrogen and sulphur are present, which gives blood red colour with due to the formation of : NaSCN (b) (c) (d) 88 / 119 The number of o-bonds, π-bonds and lone pair of electrons in pyridine, respectively are : 12, 3,0 11, 3, 1 12, 2, 1 11,2,0 89 / 119 Match List 1 with List II List I List II (Molecule) (Number and types of bond/s between two carbon atoms) Ethane I. One o-bond and two π-bonds Ethene II. Two π-bonds Carbon molecule, O2 III. One o-bond Ethyne IV. One o-bond and one π-bond Choose the correct answer from the options given below: A-III, B-IV, C-II, D-I A-III, B-IV, C-I, D-II A-I, B-IV, C-II, D-III A-IV, B-III, C-II, D-I 90 / 119 The correct statement regarding the comparison of staggered and eclipsed conformation of ethane, is: The staggered conformation of ethane is less stable than eclipsed conformation, because staggered conformation has torsional strain The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed conformation has no torsional strain The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has torsional strain The staggered conformation of ethane is more stable than eclipsed conformation, because staggered conformation has no torsional strain 91 / 119 With respect to the conformers of ethane, which of the following statements is true? Bond angle changes but bond length remains same Both bond angle and bond length change Both bond angles and bond length remains same Bond angle remains same but bond length changes 92 / 119 Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is: CH equiv CH (b) (c) (d) 93 / 119 The alkane that gives only one mono-chloro product on chlorination with $$CI_2$$ in presence of diffused sunlight is: isopentane 2,2-dimethylbutane neopentane n-pentane 94 / 119 Choose the right answer: DIBAL-H (b) Red phosphorus CaO 95 / 119 Dihedral angle of least stable conformer of ethane is: (a) (b) (c) (d) 96 / 119 Weight (g) of two moles of the organic compound, which is obtained by heating sodium ethanoate with sodium hydroxide in presence of calcium oxide is : 32 30 18 16 97 / 119 For the given reaction : (a) (b) (c) (d) 98 / 119 Given below are two statements: Statement I: The boiling point of three isomeric pentanes follows the order n-pentane > isopentane > neopentane Statement II: When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. In the light of the above statements, choose the most appropriate answer from the options given below : Statement I is correct but Statement II is incorrect. Statement I is incorrect but Statement II is correct. Both Statement I and Statement II are correct. Both Statement I and Statement II are incorrect. 99 / 119 Choose the right answer 2,3-dimethylbutane 2,2-dimethylbutane n-hexane 2-methylpentane 100 / 119 Which of the following statements, regarding the mole fraction (x) of a component in solution, is incorrect? 0 ≤ x ≤ 1 x ≤ 1 x is always non-negative -2 ≤ x ≤2 101 / 119 Molarity of liquid HCl will be, if density of solution is 1.17 g/cc: 36.5 32.05 18.25 42.10 102 / 119 1M, 2.5 litre NaOH solution is mixed with another 0.5 M. 3 litre NaOH solution. Then find out the molarity of resultant solution. 0.80 M 1.0 M 0.73 M 0.50 M 103 / 119 The mole fraction of the solution is: solute in one molal aqueous 0.009 0.018 0.027 0.036 104 / 119 25.3 g of sodium carbonate, $$Na_2CO_3$$ is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely, molar concentration of sodium ions, $$Na^+$$ and carbonate ions, $$CO_3^{2-}$$ are respectively: $$Na_2CO_3=106\;g\;mol^{-1}$$ 0.955 M and 1.910 M 1.910 M and 0.955 M 1.90 M and 1.910 M 0.477 M and 0.477 M 105 / 119 How many grams of concentrated nitric acid solution should be used to prepare 250 mL of 2.0 M $$HNO_3$$? The concentrated acid is 70% $$HNO_3$$. (a) (b) (c) (d) 106 / 119 What is the mole fraction of the solute in a 1.00 m aqueous solution? 0.177 1.770 0.0354 0.0177 107 / 119 Which of the temperature? following is dependent on Molarity Mole fraction Weight percentage Molality 108 / 119 If molality of the dilute solution is doubled, the value of molal depression constant $$\left(K_f\right)$$ will be : halved tripled unchanged doubled 109 / 119 The density of 2 M aqueous solution NaOH is $$1.28\;g/cm^3$$ The molality of the solution is : [Given that molecular mass of NaOH = $$40\;g\;mol^{-1}$$] 132 m 1.56 m 1.20 m 1.67 m 110 / 119 An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to : Increase in ionic mobility of ions 100% ionisation of electrolyte at normal dilution Increase in both i.e., number of ions and ionic mobility of ions Increase in number of ions 111 / 119 Molar conductivities at infinite dilution of respectively. Lambda deg m for will be : Molar conductivities ( Lambda deg m ) at infinite dilution of are 126.4, 425.9 and respectively. Lambda deg m for will be : (a) (b) (c) (d) 112 / 119 Limiting molar conductivity of $$NH_4OH$$ , Le Lambda $$\wedge^\circ(NH_4OH)$$ is equal to : (a) (b) (c) (d) 113 / 119 At molar conductance of 0.1 molar aqueon At of ammonium hydroxide is and at infinite dilution its molar conductance The degree or ionisation of ammonium hydroxide at the same concentration and temperature is : 20.800% 4.008% 40.800% 2.080% 114 / 119 Aqueous solution of which of the following compounds is the best conductor of electric current? (a) Hydrochloric acid, HCI (c) (d) 115 / 119 Ionic mobility of which of the following alkali metal ions is lowest when aqueous solution of their salts are put under an electric field? K Rb Li Na 116 / 119 Following limiting molar conductivity are given as : (a) x - y + 2z x + y + z x - y + z 117 / 119 The molar conductivity of 0.007 M acetic acid is . What is the dissociation constant of acetic acid? Choose the correct option. (a) (b) (c) (d) 118 / 119 The molar conductance of NaCl, HCI and at infinite dilution are 126.45, 426.16 and respectively. The molar conductance of at infinite dilution is : (a) (b) (c) (d) 119 / 119 The conductivity of centimolar solution of KCl at is $$0.0210ohm^{-1}cm^{-1}$$ and the resistance of the cell containing the solution at is 60 ohm. The value of cell constant is: (a) (b) (c) (d) Your score isThe average score is 5%